Heavy Balls on Rainy Saturdays
1The Lakeside youth soccer league plays every Saturday from September to November, rain or shine. Seventh graders Oskar Halloran and Adwoa Boateng volunteer in the league's equipment shed with Coach Imelda Barrientos. Last fall, many players complained that on rainy days some of the old match balls felt heavy and stung when they were kicked. Coach Barrientos asked Oskar and Adwoa to find out which kind of ball the league should buy next.
2A soccer ball has two main parts: an outer cover and an inner bladder that holds the air. About a hundred years ago, most balls had a leather cover, made from cowhide, stitched around a bladder of natural rubber. Natural rubber comes from latex, a milky sap collected from rubber trees. Today, most match balls have a cover of polyurethane (PU), a synthetic leather, or of polyvinyl chloride (PVC). Many bladders are now made of butyl rubber, a synthetic rubber.
3Synthetic materials are made when substances taken from natural resources react to form new substances. To make PU, small molecules made from crude oil or natural gas react and link into long chains. PVC is made from natural gas or crude oil and from ordinary salt, which supplies its chlorine atoms. Butyl rubber is made from small molecules that come from crude oil or natural gas.
4Synthetic balls have changed the game in many places. They often cost less than leather balls, so schools and leagues around the world can afford more of them, and they keep about the same weight in the rain. Synthetic materials also have costs. Crude oil and natural gas cannot be replaced once they are used up. Worn-out synthetic balls usually end up in landfills, where the plastics break down very slowly. Making and burning PVC must be done with care, because it can release harmful gases.
5For their test, Oskar and Adwoa took one ball of each kind from the shed. They pumped each ball to the same pressure and weighed it dry. They soaked each ball in a tub of water for 30 minutes, wiped it with the same towel and weighed it again. After the balls dried, the students pumped them to the same pressure once more, left them on a shelf for 7 days and measured how much of the pressure was left (Table 1).